@J some churches do have services etc. on weekdays but generally it ends up being on wed around here not monday, and it's more likely to be activities (midweek bible study, etc.) than straight-up services, so not the typical crowd of people filtering in and out
basically treat the space politely, take the boyscout mentality of 'leave your camp cleaner than you found it', and you'll be in the clear to paint the outside for sure